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Hi everybody. I am starting my guidance for NET in Chemical Sciences through this platform. I wish to inform you all that I have cleared NET and SET in chemical sciences for 10 times. I have been guiding students from last 13 years. More than 1000 students have cleared NET/SET/SLET in various subjects under my guidance. This upload will help you in preparation of NET in chemistry. I have already posted this on adichemistry before two months. This file is uploaded for new users. The content in this file is my ideas regarding preparation of NET in chemistry. It is not necessary that you should agree with my ideas. You can use my tips if you like them. Thanks to ADITYAVARDHAN for providing the platform to share my views with all of you. I apologize for grammatical and presentation errors if any. WHAT IS REQUIRED FOR CLEARING NET IN CHEMISTRY Now, I will discuss how to begin your studies for NET. Bill gates once said "If you fail to plan, you plan to fail. It means that we should have a proper plan to achieve any thing. Thus let us plan the things properly. Let us see whether we can plan our studies. I would like to quote two examples before I start guidance. Example 1: I think you might have seen in sports that players warm up before they start playing matches. Example 2: Have you noticed how the buildings are build? Initially foundation is prepared and then building is built on it. Conclusion: What these two examples teach us is that our basic knowledge (foundation) must be very good if we want to clear NET. How to improve basic knowledge: There are three steps you should follow: Step I on Day 1: Read XI standard chemistry book. Read the book very fast so that you finish reading it in 4 hours. After that read Std. XII chemistry books in next 6 hours. Step II on Day 2: Read B. Sc. Part I and II organic, inorganic and physical chemistry books. Read them very fast. Dont try to remember what you have read. Just go reading so that you finish them in a day. Step III on Day 3: Read B. Sc. III organic and inorganic books. Try to finish them reading in two to three days. If you follow this five days plan, I am sure that this knowledge will help you to solve at least 10 difficult questions in NET. When I use to tell this to students, many students use to take objection. They use to say me that why should we spend our precious time in studying XI, XII and B. Sc. books. Instead of that, we will read specialized books. Unfortunately many of such students have not cleared NET. Let us see how we should proceed further. The most important thing is to decide your target. I sincerely feel that 130 marks are sufficient to get LS and 140 marks for JRF. I suggest the following strategy to get: Section A: 20 MCQs on General Science: Our target should be of 6 MCQs Section B: 50 MCQs on Chemistry: Our target should be of 25 MCQs Section C: 75 MCQs on chemistry: Our target should be of at least of 17 MCQs. Thus, if u decide above target u score 12 + 50 + 68 = 130 Marks. PREPARATION OF PART A Let us see what we should do to get 6 MCQs correctly in NET section A. Preparation of NET section A: The most difficult part of NET preparation is this section A. As there are no clear directions from CSIR regarding the syllabus, it is challenging task to study for this part. I hate this Section. It seems that the questions are asked from mathematics. I suggest reading NDA/NA entrance exam book (Upkar publication book preferably) for this section. If u daily read this book for half an hour for a month, I am sure all of u will be able to achieve the target of 6 MCQs. Please read only maths, Part. Study the book very lightly. PREPARATION OF PART B AND C I wish to guide you regarding Chemistry preparation i.e. how to study for Section B and Section C. I have delivered more than 500 lectures on NET/SET in various Universities and Colleges. The first statement that I tell students during my lecture is "Passing NET/SET is an ART and Not SCIENCE". It means that reading hundreds of books will never help you to pass NET/SET. What you need to know is the ART of studying these hundred books. In other words, hard will never help you to pass NET/SET. Instead smart work is necessary. Let us see what I mean by smart work. PROBLEM WITH MOST OF US: The basic problem with most of us think that it is necessary to study complete syllabus. But none of us succeed doing that as the syllabus is very vast. The real fact is that it not essential to study the entire syllabus. You can pass NET/SET by studying even 60 % topics from the syllabus. The most important thing is that you should properly select your syllabus. Most of us select wrong topics for study and many a times whatever we study is not sufficient to clear NET. For example, I am organic chemist and therefore I study only organic chemistry topics and same is the thing with the students of other specialization also. Doing this, no body of us will be able to pass NET. I suggest all of you to select syllabus from two specializations for study. It is very difficult to study all the topics from syllabus as this will take lot of time and even it is not essential too I have seen students studying syllabus of one specialization getting failed in NET. Many a times students studying syllabus of two specializations getting failure n NET. The reason for the latter is our wrong selection of syllabus. For example, a friend of mine (who has completed M. Sc. in organic chemistry) came to me and told me that he want to study statistical thermodynamics. I told him that it is very difficult topic and told him to drop it from study. He denied that. He has spent 20 days for studying statistical thermodynamics. He became expert in such a hard topic. Unfortunately, when he went for NET there was only a two marks question on it. I knew that there very less weightage for this topic and therefore told him to drop it. Unfortunately my friend failed in that NET as he was a victim of wrong selection of topics. Thus, it is highly essential to the weighatge of the topics that we have selected for study. STEP I OF STUDY: Quantitative Analysis of old Papers Lets us see first step of study: Ist step: Quantitative analysis First thing that is very necessary is that u should have hard copies of previous years NET exam question papers which u can download from the csir web site (http://csirhrdg.nic.in/Question_Papers.html). The second thing is download the syllabus and get it printed. Take a June 2012 paper. Next thing that u should do is start analyzing each question. Identify the topic to which the question belongs. Write the name of topic to which the question belongs at a side of that question. In this way analyze the entire question from this paper. After this is finished, make a summary on a blank page. Use the similar method for Dec. 2012 and June 2012 paper and then Make a table as shown below (Table given below is just to show how the analysis is to be done. The weightage on the topics given in Table may be different than what is there in the papers. Topic June 2012 Dec. 2012 June 2013 Aromaticity 1 question of two 1 question of two 1 question of two marks and one marks and one marks and one question of 4 marks question of 4 marks question of 4 marks Heterocyclic 1 question of four 1 question of four 1 question of four chemistry marks marks marks Supramolecular No question No question No question No question No question No question chemistry Chemistry in nanoscience and technology (Some variation may be there in the weightage on few topics from exam to exam but it will not differ dramatically. Don t worry if you don t get any idea from this type analysis.) What we can learn from this analysis is that its of no use in studying the topics supramolecular chemistry and Chemistry in nanoscience and technology. You should select such topics on which the questions are asked in the exam. The number of topics that you should select must be sufficient to give you 120 marks. This is the first trick of study. The above analysis will require not more than six hours. I suggest all of u to do it. I feel one must do this to pass NET. STEP II OF STUDY: Qualitative Analysis of questions Once you have selected the topics, the most important part is how to study the selected topics. This is the most difficult part of NET. The biggest problem that most of us face in the exam is "we dont find any questions in the exam from the study material that we read or refer". I think most of u will agree with this. Remember that this is the problem with most of students preparing for NET in all the subjects. This happens because of our wrong method of study. Let us see what approach we should have while studying a particular topic. Let me begin a small story. This event occurred in Aug. 2006. One student came to me for the guidance regarding NET/SET. His subject was history. He was very much depressed when he came to me. He told me that he was preparing for NET/SET from last 6 years. I was shocked to hear that he has appeared for 12 SET and 12 NET exams in these years and failed in all of these exams. He asked me the reason regarding his failure. At first instance I thought that he was like most of other students preparing for NET/SET (the other students in this sentence refer to a category of students who want to clear NET/SET but have no time for study. These students prepare hardly for one month before exam for one or two hours due to which they fail in the exam). When I asked him how much time you study in day then he replied that he was preparing for 14-16 hours per day for last six years. When I heard this, I concluded that he is not like other students as mentioned in parenthesis above. It was very challenging situation for me. How can somebody fail in NET/SET exam on studying 14 hours a day for 6 years. Next, I asked him regarding the problem that he was facing. His answer was " sir, jo main padhata hoon usipe kabhi questionhi nahi ata". On getting such an answer, I asked him to specify this problem. He gave me an example which I will quote in his words: "Sir, we have history of Chatrapati Shivaji in the syllabus. I have studied history of Chatrapati Shivaji for one and half year. I have refereed most of books and even encyclopaedia concerning history of Chatrapati Shivaji. I have gained so much knowledge on history of Chatrapati Shivaji that I can write two Ph. D. thesis on him. Unfortunately, in spite of studying this much, whenever I go to NET/SET exam, I find a very different question on this topic which I am unable to solve." I was unable to guide him as I did not had any solution for his problem. The fellow went back depressed. I could not sleep that night. I was wondering for the reason regarding his failure. However, in spite of thinking on his problem for several days, I could not find any solution. However, god was kind enough to provide me solution for his problem. It was Dec. 2007, when I met a student in Pune University who has cleared NET in History. The most exciting thing about him was that he had qualified the NET when he was in M.A. Part II. When he met me, first thing he did was he touched my feet and said that he had cleared SET/NET because of my blessings. I was surprised to hear this from him since I had never seen before. He said that he had attended my lecture regarding NET/SET preparation when he was in M.A. part I and that inspired him to appear for NET/SET. I had a very good chance to compare this fellow with the one who came to me in Aug. 2006 since both were history students. I asked few questions to this fellow. I was shocked to hear that this fellow has studied only for one and half month and cleared NET (This was shocking to me because the first fellow has failed in spite of 6 years of study). I asked him regarding the method of his study. As I wanted to be more precise and therefore I asked him his method of study on the topic history of Chatrapati Shivaji. The fellow replied that he has initially analysed the questions on the topic history of Chatrapati Shivaji from the old NET exam papers. He found following questions (Plz note that the paper III was descriptive during those days and this part of syllabus is for paper III): June 2004: Describe the gold ornaments during the Chatrapati Shivajis era? Dec. 2004: Explain various silver ornaments during the Chatrapati Shivajis era? June 2005: Write an explanatory note on ornaments of pearl during Chatrapati Shivajis era? After telling these questions to me, he said to me that "from the questions asked so far, I came to the conclusion that the questions of history of Chatrapati Shivaji are based on ornaments during Chatrapati Shivajis era and therefore I searched books in Library. No book in library was available on ornaments but finally I got a book where there was illustration of ornaments used in Chatrapati Shivajis era. I studied only ornaments and nothing else. This required only 30 minutes. When I went to last NET exam which I had passed there was a question on writing a note on various copper ornaments during he Chatrapati Shivajis era? Compare two students now: One fellow is studying for one and half year on history of Chatrapati Shivaji for 14 hours a day. He can write two thesis on this topic but unfortunately he could not attempt the question in NET/SET on this topic. THE OTHER FELLOW HAS STUDIED history of Chatrapati Shivaji ONLY FOR 30 MINUTES BUT STILL HE HAS SOLVED THE QUESTION ASKED ON THIS TOPIC IN THE EXAM. This is because, first fellow has not seen what type of questions are asked in old exams. Instead, daily he use to go in library, use to get a very goof reference books on this topic and use to read the complete book from Ist page to last. The other fellow has initially analysed the questions in previous exams and has come to some sound conclusion and therefore could study exact literature on which the questions were asked. Analyse yourself now. What type of student you are? Whether type I or type II? If you are type I student then there are very less chances of passing. If you are type II student, there are more chances of your passing. Remember, we follow very orthodox method of study which never help us to pass these exams. So what is the correct method to prepare for Section B and C. For an instance, assume that you are studying valence bond theory. I suggest you to do the following: Take a blank page. Write the all questions asked on VBT in last two year exams. See whether these questions can help you to find a track of study. For an instance, most of questions on VBT are based on identification of either hybridization or geometry of complexes. This means that we must know how to find hybridization and geometry of the complexes if we want to pass NET. If you dont see the questions on VBT, then you will study ONLY assumptions of VBT and will be unable to find the geometries and hybridisation. So I suggest you to use the same method for all the selected topics. At majority of places u will come to sound conclusion. You will find that applicative questions are asked on most of the topics. We usually do not study applications. This happens because our method of study for M.Sc. is orthodox where we pay more attention towards theoretical study because in M. Sc. most of questions are starting with Describe, Explain, Write a note of....... STEP III OF STUDY: How to study Now, let me tell u how to study syllabus. I suggest you to divide your study in three parts: Part I: Prepare your own notes by using simple books Part II: Refer difficult level reference books and solve exercise given in these books. Part III: Solve at least 5000 MCQs This should be done with proper time management. For example, if i have 100 days for study, I will spend 40 days for part I, 25 days for Part II and 35 days of Part III. How to study Part I: CSIR NET syllabus is changed. The revised syllabus is just the modified version of old. The new syllabus does not give any idea regarding chemistry. For example, there is a topic called heterocyclic chemistry. If u look at heterocyclic chemistry in revised new syllabys, u dont get any idea regarding which heterocycles you should study. Similarly, there is a topic called common organic reactions. The reactions in this topic are not specified. This means that you should study at least 1000 reactions BECAUSE I think these many reactions must be common to many of us. Thus I suggest you to refer the old syllabus of NET. I am suggesting the same to all my students and most of them have cleared NET. I have heard that most of paper setters are still referring old syllabus. Also, if u see properly, u will find that revised syllabus is modification or bifurcation of old syllabus. If u look at the old syllabus, u will find that in old pattern, there were two papers. Paper I: which comprised of Section A on general science and Section B on chemistry. This paper was objective and there were 10 topics in Section B in syllabus. Paper II: which was descriptive has 34 topics for study. I suggest you to study all the ten topics from Paper I, Section B to all the students regardless of your specialization. This is because these topics are very basic and they are from organic, inorganic and physical chemistry. The names of these topics are: 1. Structure and Bonding:[Topic From Inorganic Chemistry, Major topic] 2. Acids and Bases: [Topic From Physical Chemistry, Minor topic] 3. Redox Reactions: [Topic From Physical Chemistry, Minor topic] 4.Introductory Energetics and Dynamics of Chemical Reactions: [Topic From Physical Chemistry, Major topic] 5. Aspects of s, p, d, f Block Elements: [Topic From Inorganic Chemistry, Major topic]: 6. IUPAC Nomenclature of Simple Organic and Inorganic Compounds: [Topic From Inorganic and Organic Chemistry, Monor topic] 7. Concept of Chirality: [Topic From Organic Chemistry, Major topic] 8. Common Organic Reactions and Mechanisms: [Topic From Organic Chemistry, Major topic] 9. Elementary principles and applications of electronic, vibrational, NMR, EPR, Mossbauer and mass spectral techniques to simple structural problems: [Topic From Organic and Inorganic chemistry, Major topic] 10. Data Analysis: [Topic From Inorganic chemistry, Minor topic] This was the syllabus for Paper I section B. I suggest all of u to study all the 10 topics. I have prepared the notes for all the 10 topics in which i have sincerely tried to prepare notes very systematically. I will try to provide you those notes. I have only hard copies of those notes. I will call these notes as GSR notes. I also suggest you to refer UPKAR publication book for NET in chemistry written by Taneja. I have seen the excellent notes of Aditya vardhan which he has prepared. I suggest you to use all these things for above 10 chapters. Use following method. Step I: Keep syllabus aside. For example, I am studying electronegativity from structure and bonding. What I will do is I will use GSR notes, UPKAR book and Adityas notes + one reference book of my choice. I will read electronegative simultaneously form all these four sources, understand the concept and will prepare my own notes which should be very brief. In a similar way, I will study all the other points. Step II: All these study materials GSR notes, UPKAR book and Adityas notes) have MCQs at the end of the each chapter. I will immediately solve them. In the case, if I am not able to solve any question, I will use reference books and find out the method to solve the answer of that question. Most of us simply see the answer of such question and proceed further. Step III: I have just written a book of ~2500 MCQs on these 10 chapters. It is not published yet. I suggest you solve the MCQs from this book. (The making of this book required 6 years for me). The questions in the book are of highest standard were comments of Prof. P. S. Kalasi when he saw rough copy of my book. Step IV: Iwill send u 400 mixed questions on these 10 topics. I suggest you to solve them after you finish the study of all the 10 chapters. I am sure that this will be the best method to prepare for 10 chapters. Even if u dont refer my notes, still it will not make a problem to you. In stead, you can use one more standard reference book for study. But then u should remember that I have prepared these notes for u. Us following time table: MHCET stand for Maharashtra eng.entrance exam test. u can use mCQs of ur state level exam of such type. After the syllabus, I have written names of resource material that u should follow. Some web sites are also given: 1. Structure and Bonding: Atomic orbitals, electronic configuration of atoms (L-S coupling) and the periodic properties of elements, ionic radii, ionization potential, electron affinity, electronegativity, concept of hybridization. Molecular orbitals and electronic configuration of homonuclear and heteronuclear diatomic molecules. Shapes of polyatomic molecules. VSEPR theory. Symmetry elements and point groups for simple molecules. Bond lengths, bond angles, bond order and bond energies. Resonance. Types of chemical bond (weak and strong). Intermolecular forces. Types of solids, lattice energy. GSR Notes + Upkars Book + Aditya notes (The entire syllabus in this topic is of 12th Class. Thus, solving MH-CET questions from 12th Class on this topic will be useful.) No. of Days for preparation: 5 hrs X 7 days. 2. Acids and Bases: Bronsted and Lewis acids and bases. pH and pKa, acid-base concept in non aqueous media, SHAB concept, Buffer solutions. GSR Notes + Upkars Book + Aditya notes+ AK De book (The entire syllabus in this topic is of 12th Class. Thus, solving MH-CET questions from 12th Class on this topic will be useful. Refer book of Principles of Inorganic Chemistry by Puri, Sharma and Kalia for SHAB concept.) No of Days for preparation: 5 hrs X 3 days. 3. Redox Reactions: Oxidation numbers, Redox potentials, Electrochemical series, Redox indicators. GSR Notes + Upkars Book + Aditya notes [The entire syllabus in this topic is of 12th Class. Thus, solving MH-CET questions from 12th Class on this topic will be useful. Refer electrochemistry of B. Sc. III level [Give special emphasis on emf of cells with and without transference]. Use 12th Std. book for emf series and its applications.] No of Days for preparation: 5 hrs X 3 days. 4. Introductory Energetics and Dynamics of Chemical Reactions: Law of conservation of energy. Energy and enthalpy of reactions. Entropy, free energy, relationship between free energy change and equilibrium. Rates of chemical reactions (first-and second-order reactions). Arrhenius equation and Concept of transition state. Mechanisms, including SN1 and SN2 reactions, electron transfer reactions, catalysis Colligative properties of solutions. GSR Notes + Upkars Book + Aditya notes [It is essential to study this topic to pass net/set but most of the non physical chemistry students do not study this topic and hence fail in the SET exam. To study this topic, spend three days initially to learn basic of thermodynamics. To do this, initially read only thermodynamics from 11th Std. book and then from 12th Std. book. After this read thermodynamics from B.Sc. I, II and III books. This will help you to understand basic knowledge of thermodynamics required to study syllabus of SET. After this read above mentioned study material.] (No of Days for preparation: 5 hrs X 7 days). 5. Aspects of s, p, d, f Block Elements: General characteristics of each block. Chemical principles involved in extraction and purification of common metals. Coordination chemistry, Structural aspects, isomerism, octahedral and tetrahedral crystal-field spliting of d-orbitals. CFSE, magnetism and colour of transition metal ions. Sandwich compounds metal carbonyls and metal clusters. Rare gas compounds, nonstoichiometric oxides. Radioactivity and transmutation of elements. GSR Notes + Upkars Book + Aditya notes+ AK De book (This is a major topic. To be perfect in this topic one needs to study the entire inorganic section topics of paper III. This will help twofold. You will be able to solve 10 descriptive questions from Paper III and all the objective questions asked from paper II on this topic since all the inorganic syllabus of paper III is a part of this topic. Read B. Sc. II and III coordination chemistry to learn basics of coordination chemistry and then start studing coordination chemistry of this topic.) (No of Days for preparation: 5 hrs X 7 days). 6. IUPAC Nomenclature of Simple Organic and Inorganic Compounds: GSR Notes + Aditya notes+ e-net + AK De book for Inorganic nomenclature Study the nomenclature of common inorganic compounds from Principles of Inorganic Chemistry by Puri, Sharma and Kalia and use e-net for organic nomenclature (use the following sites) http://www.cem.msu.edu/~reusch/VirtualText/nomen1.htm http://www.goiit.com/posts/show/813814/common-names-and-geneva-system--nomenclature-ofbicyclic-compounds-804379.htm (No of Days for preparation: 5 hrs X 2 days). 7. Concept of Chirality: Recognition of symmetry elements and chiral structures, R-S nomenclature, diastereoisomerism in acyclic and cyclic-systems, E-Z isomerism. Conformational analysis of simple cyclic (chair and boat cyclohexanes) and acyclic systems, Interconverison of Fischer, Newman and Sawhorse projections. GSR Notes + Aditya notes+ Book on Stereochemistry by P S Kalasi + B. Sc. III sterechemistry (Take the help of a teacher to learn R/S nomenclature and for learning Sawhorse, Newmann projection formulae. This is becoz stereochemistry is 3-diamensional study and thus difficult to study by reading study material written on plane paper as it.) (No of Days for preparation: 5 hrs X 4 days). 8. Common Organic Reactions and Mechanisms: Reactive intermediates. Formation and stability of carbonium ions, carbenes, nitrenes, radicals and arynes. Nucleophilic, electrophilic, radical substitution, addition and elimination reactions. Familiar name reactions : Aldol, Perkin, Stobbe, Dieckmann condensations ; Hofmann, Schmidt, Lossen, Curtius, Beckmann and Fries rearrangements, Reimer-Tiemann, Reformatsky and Grignard reactions. Diels-Alder reaction, Claisen rearrangement, Friedel-Crafts reaction, Witting reaction. Routine functional group transformations and inter-convertions of simple functionalities. Hydroboration, Oppenauer oxidation, Clemmensen, Wolf-Kishner, MeerweinPonndorf Verley and Birch reductions. GSR Notes + Aditya notes+ Sanyal Book of organic reactions + Rean. Mechn. Book by Kalasi (Make a short summary of all reactions in tabular form. Study oxidation, reduction and elimination recations since many questions are asked on them. There is no need to study mechanism of each reaction. Remember only the intermediates.) (No of Days for preparation: 5 hrs X 8 days). 9. Elementary principles and applications of electronic, vibrational, NMR, EPR, Mossbauer and mass spectral techniques to simple structural problems: It is difficult to study spectroscopy by reading the notes. It is a long process to learn spectroscopy. One needs to develop the problem solving approach. You can read number of books. Recently an excellent problem based book is available (Organic spectroscopic Structure determination by Douglss F. Taber 0xford Uni. Press. Some part of this book is available on enet: http://valhalla.chem.udel.edu/SpecBook.pdf You can also use other famous books on spectroscopy written by Parikh, Pavia , P. S. Kalasi and Y. R. Sharma. (No of Days for preparation: 5 hrs X 7 days). 10. Data Analysis: Types of errors, propogation of errors, accuracy and precision, least-square analysis, average standard deviation. GSR Notes + Aditya notes (Use Principles of Inorganic Chemistry by Puri, Sharma and Kalia for deviation concept. Use enet for significant numbers and rounding off in calculations and logarithmic calculations.) http://cstl.syr.edu/fipse/Decunit/roundec/roundec.htm http://www.citycollegiate.com/chapter1XI.htm (No of Days for preparation: 5 hrs X 2 days) Let us see now, how to deal with Paper II preparation There were 34 topics in this paper. They are as follows: 1. Quantum Chemistry: 2. The variation method and pertubation theory 3. Born-Oppenheimer approximation, Hydrogen molecule ion 4. Group theoretical representations and quantum mechanics 5. Spectroscopy 6. Thermodynamics 7. Chemical Equilibrium 8. Ideal and Non-ideal Solutions 9. Equilibria in Electrochemical Cells 10. Surface Phenomena 11. Statistical Thermodynamic probability and entropy 12. Non-equilibrium Thermodynamics 13. Reaction Kinetics 14. Fast Reactions 15. Macromolecules 16 Solids 17. Nuclear Chemistry 18. Chemistry of Non-transition Elements 19. Chemistry of Transition Elements 20. Chemistry of Lanthanides and Acitindes : 21. Organometallic Chemistry of Transition Elements 22. Topics in Analytical Chemistry 23. Bioiorganic Chemistry 24. Aromaticity 25. Stereochemistry and Conformational Analysis : 26. Selective Organic Name Reactions 27. Mechanisms of Organic Reactions 28. Pericyclic Reactions : 29. Heterocycles 30. Reagents in Organic Synthesis 31. Chemistry of Natural Products 32. Bioorganic Chemistry 33. Photochemistry 34. Spectroscopy There are 15 topics from physical, 7 topics from inorganic, 11 topics from organic and 1 topic from analytical chemistry. I suggest all of u to study syllabus of any two specializations. Dont consider analytical as specialization. I suggest the following selection: Organic chemistry students: Study all organic topics (except natural products) + All inorganic topics Inorganic chemistry students: Study all organic topics (except natural products) + All inorganic topics Physical Chemistry students: Study majority of physical chemistry topics and all inorganic topics plus some esay organic topics like reagents and selective organic reactions Analytical chemistry students: Study all organic topics (except natural products) + All inorganic topics + Analytical chemistry topic. I have prepared the following table for organic, inorganic and analytical chemistry students. These students can choose following topics: TOPIC DISTRIBUTION Organic Chemistry Physical Chemsitry No. of Topics = 15 x Inorganic Chemistry No. of Topics = 07 No. of Topics = 11 Solids Aromaticity Quantum Chem. Analytical Chemistry No. of Topics = 01 Topics in Analytical Analytical Chemistry x The variation method.... Nuclear Chemistry x Born-Oppenheimer.... Chem. of Non Transition x Quantum Mechanics Chem. of Transition x Spectroscopy x Thermodynamics x Chemical equlibrium x Ideal& non ideal soln x Equilibria in elctro. Cells x Surface phenomena x Stastical Thermo. x Non. equlibrium Thermo. Photochemistry Reaction Kinetics Spectroscopy x Stereochemistry Name Reactions Mechanisms of Org. Rean. Lanthanides & Acti. Pericyclic Reactions Organometallic Chem. Heterocycles Bioinorganic chem. x Reagents x Natural Products x Bioorganic Chem. Fast Reactions Macromolecules (Plz remember that this my suggestion. The selection should depend on ur abilities. If u study more topics, it is well and good. ) I suggest you to use following books for preparation. I have prepared notes for all the topics of inorganic chemistry. I can provide with u these notes. When I was preparing the notes for this section, most of students and colleagues use to criticize me and use to suggest me to prepare notes for organic section. As I was from organic chemistry, it would have been easy job for me to prepare organic notes instead of inorganic. But I decided to prepare inorganic chemistry notes. The reason for this was that I was knowing that most of M.Sc. chemistry students have organic specialization. They will easily study organic but will not take inorganic seriously. Thus, I have prepared the noted of Inorganic. They have benefited the students of all specializations except (inorganic). This is because students of phy. org. and ana. can study the syllabus from their specialization easily and the inorganic section notes which I have prepared help them to do study conveniently. I dont have organic chemistry notes. I have never taken any efforts to prepare them because I was knowing that students of organic chemistry can study the syllabus provided the names of the books are suggested to the. Thus, I have given the names of reference books. I have not suggested the names of the books for physical chemistry as I have not studied for this specialization. I have read the notes of Aditya which are the best notes that I have ever seen. I suggest all of u to use that as common to all the following topics. I have given below the method for preparation of inorganic and inorganic notes mentioned above. Solids: Dislocations in solids, Schottky and Frenkel defects. Electrical properties. Insulators and semiconductors, band theory of solids, solid-state reactions. Time for study: [5 hrs x 3 days] Reference books: GSR notes. Use B. Sc. III book and Concise Inorganic Chemistry by J. D. Lee for crystal structures of common ionic compounds. Use the web sitehttp://chemed.chem.purdue.edu/genchem/topicreview/bp/ch13/unitcell.php for crystal structures of ionic compounds. Use Solid state Chemistry by A. H. Hanney for solid state reactions. Use B. Sc. III Chemistry book for Semiconductors. Consult physics teacher for magnetic susceptibility, superconductors and their types and Meissner effect. Nuclear Chemistry: Radioactive decay and equilibrium. Nuclear reactions, Q value, crosssections, types of reactions. Chemical effects of nuclear transformations, fission and fusion, fission products and fission yields. Radioactive techniques, tracer techniques, neutron activation analysis, counting techniques such as G.M., ionization and proportional counters Time for study: [5 hrs x 3 days] Reference books: Use 12th Std. book for problems on radioactivity. Use Essentials of Nuclear Chemistry by H. J. Arnikar for types of nuclear reactions, Q value, nuclear cross section, isotope dilution technique, NAA and tracer technique. B. Sc. III book for nuclear fusion, fission and nuclear reactors. Give more attention on problem solving on NAA, isotope dilution techniques and reaction cross section. You can use GSR notes also. Chemistry of Non-transition Elements: General discussion on the properties of the nontransition elements, special features of individual elements, synthesis, properties and structure of their halides and oxides, polymorphism of carbon, phosphorus and sulphur. Synthesis, properties and structure of boranes, carboranes, borazines, silicates, carbides, silicones, phosphazenes, sulphur, oxyacids of nitrogen, phophorus, sulphur and halogens. Interhalogens, pseudohalides and noble gas compounds. Time for study: [5 hrs x 5 days] Reference books: Use AK De book (refer the entire book) for small beat type question asked on this topic. Give more emphasis on all structures in this topic since most of the times the questions are asked to draw the structures. Use Inorganic Chemistry by Shriver and Atkins as a reference book for entire topic. You can use GSR notes also. Chemistry of Transition Elements:Coordination chemistry of transition metalions. Stability constants of complexes and their determination, stabilization of unusual oxidation states. Stereochemistry of coordination compounds. Ligand field theory, spliting of d-orbitals in low symmetry environments. Jahn-Teller effect, interpretation of electronic spectra including charge transfer spectra, spectrochemical series, nephelauxetic series. Dia-para-ferro and antiferromagentism, quenching of orbital angular moments, spin orbit coupling. Inorganic reaction mechanisms, substitution reactions, trans-effect and electron transfer reactions, photochemical reactions of chromium and ruthenium complexes. Fluxional molecules. Iso and heteropolyacids, metal clusters. Spin crossover in coordination compounds. Time for study: [5 hrs x 10 days] Reference books: Initially learn coordination chemistry from B. Sc. II and III book. Then study GSR notes. For VBT, CFT and MOT use Principles of Inorganic Chemistry by Puri, Sharma & Kalia and Concise Inorganic Chemistry by J D Lee. For small beats on this topic especially on colors of coordination compounds use AK De book. The best book for co-ordination chemistry is Concise Coordination Chemistry by R. Gopalan and V. Ramalingam. For problems on JahnTellar effect see Inorganic Chemistry by Shriver and Atkins and AK De book. For inorganic reaction mechanisms see Principles of Inorganic Chemistry by Puri, Sharma and Kalia. Use Basic Inorganic Chemistry: F. Albert Cotton for fluxional molecules. Use Inorganic Chemistry by J. O. House for thorough knowledge of entire topic especially for spectra, orgel diagrams and reactions of coordination compounds.You can use GSR notes also. Chemistry of Lanthanides and Actinides: Spectral and magnetic properties, use of lanthanide compounds as shift reagents. Time for study: [5 hrs x 3 days] Reference books: Use B. Sc.III book for general notes on lanthanides. AK De book for general questions on this topic. Use Concise Inorganic Chemistry by J D Lee for magnetic moments and complexes of lanthanides and actinides. You should be able to compare each of the property (magnetic moments, colors, etc) of lanthanides with that of actinides or transition elements. Use Spectroscopy by P. S. Kalasi for lanthanide shift reagents. Learn to determine to the ground state term symbols of lanthanides using any book.You can use GSR notes also. Organometallic Chemistry of Transition Elements: Synthesis, structure and bonding, organometallic reagents in organic synthesis and in homogeneous catalytic reactions (hydrogenation, hydroformylationn, isomerisation and polymerisation), pi-metal complexes, activation of small molecules by coordination. Time for study: [5 hrs x 4 days] Reference books: Use Inorganic Chemistry by G. L. Miessler & D. A. Tarr as a reference book for the entire syllabus of this topic. Use Inorganic Chemistry by J. O. House for metal carbonyls and sandwich compounds. Use the same book or book of Inorganic Chemistry by Shriver and Atkins for homogeneous catalytic reactions like Wacker process, hydrogenation using Wilkinsons Catalyst, Monsanto process and Ziegler Natta catalysis. Give special emphasis on 18-electron rule and use of IR spectroscopy in metal carbonyls. You can use GSR notes also. Bioinorganic Chemistry: Molecular mechanism of ion transport across membranes, ionophores. Photosynthesis-PS-I, PS-II, nitrogen fixation, oxygen uptake proteins, cytochromes and ferrodoxions. Time for study:[5 hrs x 4 days] Reference books: Use Inorganic Chemistry by G. L. Miessler & D. A. Tarr; Inorganic Chemistry by J. O. House and AK De book for different points in the syllabus of bioinorganic chemistry. Give more emphasis of hemoglobin and myoglobin. The question like match the following are usually asked for 7 marks on this topic. You should be able to draw active site and write the working in short for all molecules in bioinorganic chemistry. You can use GSR notes also. Aromaticity: Huckel s rule and concept of aromaticity : annulenes and heteroannulenes, fullerenes. (C60) Time for study: [5 hrs x 2 days] Reference books: You should be able to classify any compound as aromatic, antiaromatic, quasi aromatic and non aromatic. Give stress on aromaticity in cyclic olefins, heterocyclic compounds, annulenes, fulvenes, fulvalenes and polycyclic compounds. Study spectral characteristics of C60, its preparation, its aromaticity and chemical reactions from e-net. Also study temperature dependence PNMR spectra annulenes. Use Advanced Organic Chemistry by Jerry March ( Page 37-66) for basic concepts. http://www.mnstate.edu/jasperse/Chem360/Handouts/Ch%2016%20Handouts%20(all).pdf Use this site for brief notes on aromaticity. http://www.uea.ac.uk/~c286/aromaticnotes.htm Use this site for brief notes on aromaticity. Problems in Aromatic Chemistry by Samuel Delvin use this book as a reference book (if it is easily available otherwise use e-net material by searching various sites placing aromaticity keyword on www.google.co.in) Selective Organic Name Reactions: Favorskii reaction, Strok enamine reaction, Michael addition, Mannich reaction, Sharpless asymmetric expoxidation, ene reaction, Barton reaction, Hofmann Loffler-Freytag reaction, Shapiro reaction, Baeyer-Villiger reaction, Chichibabin reaction. Time for study: [5 hrs x 3 days] Reference books: More emphasis should be given on problems based on the syllabus. Use following books for this topic Organic Reactions and Their Mechanisms by P. S. Kalsi Some Modern Methods of Organic Synthesis by W. Carruthers Reactions Rearrangements and Reagents by S.N. Sanyal Organic Chemistry by Clayden, Greeves, Warren and Wothers. Organic Reaction Mechanism : Including Reaction Intermediates by V.K. Ahluwalia. Each day study one new reaction that is not in the syllabus from any book. If you do so then you will be able to solve one question on reagents and reactions which is on common reagents and reactions that are not in the syllabus. Give more emphasis on elimination reactions since such question is usually concentrated on them. Mechanisms of Organic Reactions: Labelling and kinetic isotope effects, Hamett equation, (sigma-rho) relationship, non-classical carbonium ions, neighbouring group participation. Time for study: [5 hrs x 4 days] Reference books: More emphasis should be given on Hammett equation i.e. sigma & rho values and NGP reactions. For last many years there has been no question on Kinetic isotope effect. Use following books for this topic Organic chemistry by Clayden, Greeves, Warren and Wothers for Hammett equation. Use Advanced Organic Chemistry by Jerry March for NGP reaction (Pp 269-286) and labeling technique (Pp 197) Organic Reactions and Their Mechanisms P. S. Kalsi for NGP reaction. Organic Reaction Mechanisms by R. K. Bansal for kinetic isotope effects. Structure and Mechanism of Organic Chemistry by E.S. Gould as a reference book or entire topic. Pericyclic Reactions: Selection rules and stereochemistry of electrocyclic reactions, cycloaddition and sigmatrophic shifts, Sommelet-Hauser, Cope and Claisen rearrangements. Time for study: [5 hrs x 5 days] Reference books: Do not study theory in deep. More emphasis should be given on problem solving approach. One must strictly learn to determine selection rule and stereo chemistries of problems on pericyclic reactions. Study chelotropic reactions and 1,3-dipolar additions. Use following books for this topic. Organic chemistry by Clayden, Greeves, Warren and Wothers. Organic Reactions and Their Mechanisms P. S. Kalsi. Advanced Organic Chemistry by Jerry March. Some modern methods of Organic synthesis by W. Carruthers Organic Chemistry by Morrison and Boyd Pericyclic reactions by Roland Lehr and Alan Merchand (if easily available) Use the following sites: http://www.ch.ic.ac.uk/GIC/pericyclic/ http://www.meta-synthesis.com/webbook/49_pericyclic/pericyclic.html http://usm.maine.edu/~newton/Chy251_253/Lectures/Pericyclic/PericyclicFS.html Heterocycles: Synthesis and reactivity of furan, thiophene, pyrrole, pyridine, quinoline, isoquinoline and indole. Skraup synthesis, Fischer indole synthesis. Time for study: [5 hrs x 5 days] Reference books: More emphasis should be given on synthesis and reactions of heterocycles. Study the important synthesis of heterocycles rather than studying the all the reported synthesis. Synthesis should be studied in general and it should not restrict to the few molecules. Most of the time retro synthesis type of question is asked on the synthesis of heterocycles. See old question papers to get the idea of questions on synthesis part. Use B. Sc. III organic book for common heterocycles. Use following books for this topic. Organic chemistry by Clayden, Greeves, Warren and Wothers. Heterocyclic chemistry by R. K. Bansal Reagents in Organic Synthesis: [5 hrs x 7 days] More emphasis should be given on applications of reagents. Use the following books Organic Reactions and Their Mechanisms P. S. Kalsi. Reactions Rearrangements And Reagents by S.N. Sanyal Organic Reaction Mechanism : Including Reaction Intermediates by V.K. Ahluwalia. Some modern methods of Organic synthesis by W. Carruthers Organic chemistry by Clayden, Greeves, Warren and Wothers Organic book by Jagdamba singh For metal complex hydrides use W. Carruthers and Jerry March book (Page 1093 onwards). See questions on crown ethers, phase transfer catalysts and Merrifield resin asked in previous question papers to get the idea regarding the approach of study. Study two new reagents that are not in the syllabus every day from any book so that you will be able to solve one question on reagents and reactions that include applications of common reagents (that are not in the syllabus) used in organic chemistry. Study oxidizing agents from Jerry March and W. Carruthers book Photochemistry: Principles of energy transfer, cis-trans isomerization, Paterno-Buchi reaction, Norrish Type I and II reactions, photoreduction of ketones, di-pi-methane rearrangement, photochemistry of arenes. Time for study: [5 hrs x 5 days] Reference books: More emphasis should be given on problems. Use following books Organic Reactions and Their Mechanisms P. S. Kalsi. Introduction to Organic Photochemistry by J. D. Coyle Photochemistry and Pericyclic reactions by Jagdamba Singh Study entire photochemical reactions given in Organic Reactions and Their Mechanisms P. S. Kalsi. And then refer J. D. Coyle book for learning all the reactions in detail. General comments: For bio-organic and Stereochemistry and Conformational Analysis: I suggest u to use reference books of ur choice. Recently I have seen that most of organic chemistry questions in NET exam are from ORGANIC SYNTHESIS BY SMITH. You must have this book if u want to clear NET (JRF). I have prepared six months planner for the study also. 180 DAYS STUDY-PLAN FOR NET Day Topic Time Remark 1-7 Structure and Bonding 5 hrs Detail Study 8-10 Acids and Bases 5 hrs Detail Study 11-14 Redox reactions 5 hrs Detail Study 15-21 Introductory energetics and Dynamics 5 hrs Detail Study 22-28 Aspects of s.p.d.f block elements 5 hrs Detail Study 29-31 IUPAC nomenclature 5 hrs Detail Study 32-36 Concept of chirality 5 hrs Detail Study 37-44 Common organic reactions 5 hrs Detail Study 45-51 Spectroscopy 5 hrs Detail Study 52-53 Data analysis 5 hrs Detail Study Day Topic Time Remark Topic Time Remark 54-56 Solids 5 hrs Detail Study Structure and bonding 1 hr I revision 57-59 Nuclear chemistry 5 hrs Detail Study Acids and Bases 1 hr I revision 60-65 Chemistry of non transition elements 5 hrs Detail Study Introductory energetics and Dynamics 1 hr I revision 66-76 Chemistry of non transition elements 5 hrs Detail Study Aspects of s.p.d.f block elements 1 hr I revision 77-79 Chemistry of lanthanides and actinides 5 hrs Detail Study Acids and bases 1 hr I revision 80-84 Organometallic chemistry of transition elements 5 hrs Detail Study Common organic reactions 1 hr I revision 85--88 Bioinorganic Chemistry 5 hrs Detail Study Common organic reactions 1 hr I revision 89-91 Aromaticity 5 hrs Detail Study Stereochemistry 1 hr I revision 92-95 organic name reactions 5 hrs Detail Study Data analysis 1 hr I revision and Nomenclature 96-99 Mechanisms of organic reactions 5 hrs Detail Study Solids 1 hr I revision 100-105 Pericyclic reactions 5 hrs Detail Study Chemistry of non transition elements 1 hr I revision 106-110 Heterocycles 5 hrs Detail Study Organometallic chemistry of transition elements 1 hr I revision 111-118 Reagents 5 hrs Detail Study Chemistry of transition elements 1 hr I revision 119-122 Photochemistry 5 hrs Detail Study Nuclear chemistry 1 hr I revision 123 Bioinorganic chemistry 6hrs I revision 124 Aromaticity 3 hrs I revision Structure and bonding 3 hr II revision 125 Organic name reactions 3 hrs I revision Acids &Bases 3 hr II revision 126 Organic name reactions 3 hrs I revision Redox reactions 3 hr II revision 127-128 Mechanisms of organic reactions 3 hrs I revision Introductory energetics and Dynamics 3 hr II revision 129-130 Pericyclic reactions 3 hrs I revision Aspects of s.p.d.f block elements 3 hr II revision 131-132 Heterocycles 3 hrs I revision Data analysis 3 hr II revision and Nomenclature 133-135 Reagents 3 hrs I revision Common organic reactions 3 hr II revision 136 Photochemistry 3 hrs I revision Spectroscopy 3 hr II revision 137 Photochemistry 3 hrs I revision Stereochemistry 3 hr II revision 138 Aromaticity 3 hrs II revision Solids 3 hr II revision Day Topic Time Remark 139 Organic name reactions 3 hrs II revision Nuclear chemistry 3 hr II revision 140 Mechanisms of organic reactions 3 hrs II revision Chemistry of non transition elements 3 hr II revision 141 Pericyclic reactions 3 hrs II revision Chemistry of transition elements 3 hr II revision 142 Heterocycles 3 hrs II revision Organometallic chemistry of transition elements 3 hr II revision 143 Reagents 3 hrs II revision Lanthanides and actinides 3 hr II revision 144 Photochemistry 3 hrs II revision Bioinorganic chemistry 3 hr II revision 145 Structure and Bonding 2 hrs III revision 146 Acids and Bases 2 hrs III revision 147 Redox reactions 2 hrs III revision 148 Introductory energetics and Dynamics 2 hrs III revision 149 Aspects of s.p.d.f block elements 2 hrs III revision 150 IUPAC nomenclature 2 hrs III revision 151 Concept of chirality 2 hrs III revision 152 Common organic reactions 2 hrs III revision 153 Spectroscopy 2 hrs III revision 154 Data analysis 2 hrs III revision Day 155-170: SOLVING ALL OLD QUESTION PAPERS Day 170-180: LAST and 4th Revision You can send e-mail gajananrashinkar@gmail.com for GSR notes. I will tell details about my notes. I have uploaded this file to guide you. This is not uploaded to promote my notes. You can follow this post if you like it. BEST OF LUCK.
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